The time-asymmetric quantum state exchange mechanism

TL;DR

This paper demonstrates that in non-adiabatic, decaying quantum systems, forward and reverse time protocols with chirped laser pulses produce different final states, revealing time-asymmetry around exceptional points.

Contribution

It introduces a novel time-asymmetric quantum state exchange mechanism based on non-adiabatic couplings near exceptional points in laser-driven molecular systems.

Findings

Positively and negatively chirped pulses lead to different vibrational states.

The phenomenon occurs around exceptional points in parameter space.

The results suggest a new way to observe exceptional points experimentally.

Abstract

We show here that due to non-adiabatic couplings in decaying systems applying the same time-dependent protocol in the forward and reverse direction to the same mixed initial state leads to different final pure states. In particular, in laser driven molecular systems applying a specifically chosen positively chirped laser pulse or an equivalent negatively chirped laser pulse yields entirely different final vibrational states. This phenomenon occurs when the laser frequency and intensity are slowly varied around an exceptional point (EP) in the laser intensity and frequency parameter space where the non-hermitian spectrum of the problem is degenerate. The protocol implies that a positively chirped laser pulse traces a counter-clockwise loop in time in the laser parameters' space whereas a negatively chirped pulse follows the same loop in the clockwise direction. According to this protocol one can choose the final pure state from any initial state. The obtained results imply the intrinsic non-adiabaticity of quantum transport around an EP, and offer a way to observe the EP experimentally in time-dependent quantum systems.