Kinetics of heterogeneous nucleation and growth: An approach based on a grain explicit model

TL;DR

This paper introduces a grain explicit model (GEM) for phase transitions on grain boundaries, providing accurate predictions across various nucleation processes and clarifying the transition between different regimes.

Contribution

The paper presents a novel grain explicit model (GEM) that improves predictions of heterogeneous nucleation and growth by incorporating granular structure effects.

Findings

GEM accurately predicts nucleation processes across different regimes.

A transition scale based on material properties distinguishes regimes.

Relationships between Avrami exponents and regimes are clarified.

Abstract

A model for phase transitions initiated on grain boundaries is proposed and tested against numerical simulations: this approach based on a grain explicit model (GEM) allows to consider the granular structure, yielding accurate predictions for a wide span of nucleation processes. Comparisons are made with classical models of homogeneous (JMAK) as well as heterogeneous (Cahn) nucleation. A transition scale based on material properties is proposed, allowing to discriminate between random and site saturated regimes. Finally, we discuss the relationship between an Avrami type exponent and the transition regime, drawing conditions for its extraction from experiments.