Thermal properties of graphene: Fundamentals and applications

TL;DR

This paper reviews the fundamental thermal properties of graphene, emphasizing its high in-plane conductivity, anisotropic heat flow, and potential applications in thermal management and electronics.

Contribution

It provides a comprehensive overview of graphene's thermal behavior, including effects of substrates, defects, and modifications, highlighting its potential for innovative heat flow control.

Findings

Graphene exhibits over 100-fold anisotropy in heat flow.

High in-plane thermal conductivity up to certain channel lengths.

Interfaces and contacts are key bottlenecks for heat dissipation.

Abstract

Graphene is a two-dimensional (2D) material with over 100-fold anisotropy of heat flow between the in-plane and out-of-plane directions. High in-plane thermal conductivity is due to covalent sp2 bonding between carbon atoms, whereas out-of-plane heat flow is limited by weak van der Waals coupling. Herein, we review the thermal properties of graphene, including its specific heat and thermal conductivity (from diffusive to ballistic limits) and the influence of substrates, defects, and other atomic modifications. We also highlight practical applications in which the thermal properties of graphene play a role. For instance, graphene transistors and interconnects benefit from the high in-plane thermal conductivity, up to a certain channel length. However, weak thermal coupling with substrates implies that interfaces and contacts remain significant dissipation bottlenecks. Heat flow in graphene or graphene composites could also be tunable through a variety of means, including phonon scattering by substrates, edges or interfaces. Ultimately, the unusual thermal properties of graphene stem from its 2D nature, forming a rich playground for new discoveries of heat flow physics and potentially leading to novel thermal management applications.