Approaching quantum criticality in a partially geometrically frustrated heavy-fermion metal

TL;DR

This paper reports the observation of a quantum phase transition in a partially frustrated heavy-fermion metal, revealing a potential new route to quantum criticality involving geometric frustration, magnetic order, and Kondo effects.

Contribution

It demonstrates a quantum phase transition in a frustrated antiferromagnetic metal with partial magnetic order, highlighting the role of geometric frustration in quantum critical behavior.

Findings

Quantum critical point achieved by Ni substitution in CePdAl.

Specific heat shows -log T dependence near criticality.

Frustration induces two-dimensional antiferromagnetic fluctuations.

Abstract

Quantum phase transitions have captured the interest of a large community in condensed-matter and atom physics research. The common feature of these very different material classes lies in the fact that the competition between low-energy scales can be tuned by a nonthermal parameter, such as pressure, magnetic or electric field, and chemical composition for the condensed-matter systems. In heavy-fermion materials, the strong exchange J between f-electrons and conduction electrons can lead to quenching of the f-electron-derived (nearly) localized magnetic moments via the Kondo effect or, if J becomes weaker, to long-range magnetic order via the Ruderman-Kittel-Kasuya-Yosida interaction mediated by the conduction electrons. In addition it has been suggested that magnetic order can be suppressed by quantum fluctuations which may be enhanced by geometric frustration. Here we report on the observation of a quantum phase transition in a partially frustrated antiferromagnetic metallic system. In antiferromagnetic CePdAl the magnetic Ce ions form a network of equilateral triangles in the (001) plane, similar to the kagom\'e lattice, with one third of the Ce moments not participating in long-range order. The N\'eel temperature T_N = 2.7 K can be driven to zero upon replacing 14.4% of Pd by Ni. Here the specific heat C exhibits a C/T ~ - log T dependence. Within the Hertz-Millis-Moriya model of quantum criticality, this behavior can be attributed to two-dimensional critical antiferromagnetic fluctuations arising from the decoupling of three-dimensional magnetic order by frustration. The intermediate planes of frustrated moments are a possible candidate for a two-dimensional spin-liquid. The simultaneous presence of magnetic order, geometric frustration, and Kondo effect in this system might thus entail a new route to quantum criticality.