Pure rotational spectra of TiO and TiO_2 in VY Canis Majoris
T. Kaminski, C. A. Gottlieb, K. M. Menten, N. A. Patel, K. H. Young,, S. Brunken, H. S. P. Muller, M. C. McCarthy, J. M. Winters, L. Decin

TL;DR
This study reports the first detection of pure rotational lines of TiO and TiO_2 in the circumstellar environment of VY CMa, providing insights into dust formation processes around cool oxygen-rich stars.
Contribution
It presents the first observational detection of TiO and TiO_2 rotational spectra in a stellar envelope, highlighting their potential role in dust seed formation.
Findings
TiO and TiO_2 detected in VY CMa's envelope
Derived rotational temperature of about 250 K for TiO_2
Indicates a significant amount of oxides remain gaseous, not forming dust
Abstract
We report the first detection of pure rotational transitions of TiO and TiO_2 at (sub-)millimeter wavelengths towards the red supergiant VY CMa. A rotational temperature, T_rot, of about 250 K was derived for TiO_2. Although T_rot was not well constrained for TiO, it is likely somewhat higher than that of TiO_2. The detection of the Ti oxides confirms that they are formed in the circumstellar envelopes of cool oxygen-rich stars and may be the "seeds" of inorganic-dust formation, but alternative explanations for our observation of TiO and TiO_2 in the cooler regions of the envelope cannot be ruled out at this time. The observations suggest that a significant fraction of the oxides is not converted to dust, but instead remains in the gas phase throughout the outflow.
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