Synthesis of Nanoparticles of the Giant Dielectric Material, CaCu3Ti4O12 from a Precursor Route

TL;DR

This paper reports a novel precursor route for synthesizing phase-pure CaCu3Ti4O12 nanoparticles with high dielectric constants and low losses, suitable for advanced dielectric applications.

Contribution

It introduces a new complex oxalate precursor synthesis method for CaCu3Ti4O12 nanoparticles with controlled size and excellent dielectric properties.

Findings

Nanoparticles sized 30-80 nm were synthesized.

The resulting ceramics exhibited dielectric constants up to 40000.

Low dielectric loss of less than 0.07 was achieved.

Abstract

A complex oxalate precursor, CaCu3(TiO)4(C2O4)8.9H2O, was synthesized and the precipitate that obtained was confirmed to be monophasic by the wet chemical analyses, X-ray diffraction, FTIR absorption and TG, DTA analyses. The thermal decomposition of this oxalate precursor led to the formation of phase-pure calcium copper titanate, CaCu3Ti4O12, at 680oC. The bright field TEM micrographs revealed that the size of the as synthesized crystallites to be in the 30 to 80 nm range. The powders so obtained had excellent sinterability resulting in high density ceramics which exhibited giant dielectric constants upto 40000 (1 kHz) at 25oC accompanied by low dielectric losses, less than 0.07.