The abundance of HCN in circumstellar envelopes of AGB stars of different chemical types

TL;DR

This study presents a detailed survey of HCN emission in AGB stars, revealing how HCN abundance varies with star type and C/O ratio, and providing constraints for chemical models.

Contribution

It provides the first comprehensive non-LTE analysis of HCN in a large, diverse sample of AGB stars, improving abundance estimates and model constraints.

Findings

HCN abundance is highest in carbon stars, lower in S-type, and lowest in M-type AGB stars.

HCN envelope sizes are consistent with previous interferometric results.

HCN abundances in M-type stars are higher than thermal equilibrium predictions, challenging existing models.

Abstract

A multi-transition survey of HCN (sub-) millimeter line emission from a large sample of AGB stars of different chemical type is presented. The data are analysed and circumstellar HCN abundances are estimated. The sample stars span a large range of properties such as mass-loss rate and photospheric C/O-ratio. The analysis of the new data allows for more accurate estimates of the circumstellar HCN abundances and puts new constraints on chemical models. In order to constrain the circumstellar HCN abundance distribution a detailed non-LTE excitation analysis, based on the Monte Carlo method, is performed. Effects of line overlaps and radiative excitation from dust grains are included. The median values for the derived abundances of HCN (with respect to H2) are 3x10-5, 7x10-7 and 10-7 for carbon stars (25 stars), S-type AGB stars (19 stars) and M-type AGB stars (25 stars), respectively. The estimated sizes of the HCN envelopes are similar to those obtained in the case of SiO for the same sample of sources and agree well with previous results from interferometric observations, when these are available. We find that there is a clear dependence of the derived circumstellar HCN abundance on the C/O-ratio of the star, in that carbon stars have about two orders of magnitude higher abundances than M-type AGB stars, on average. The derived HCN abundances of the S-type AGB stars have a larger spread and typically fall in between those of the two other types, however, slightly closer to the values for the M-type AGB stars. For the M-type stars, the estimated abundances are much higher than what would be expected if HCN is formed in thermal equilibrium. However, the results are also in contrast to predictions from recent non-LTE chemical models, where very little difference is expected in the HCN abundances between the various types of AGB stars.