Extremely metal-poor gas at a redshift of 7
Robert A. Simcoe, Peter W. Sullivan, Kathy L. Cooksey, Melodie M. Kao,, Michael S. Matejek, and Adam J. Burgasser

TL;DR
This study reports the first direct measurement of extremely low heavy element abundance in gas at redshift 7, providing insights into the universe's primordial state and early star formation conditions.
Contribution
It presents the first direct detection of near-primordial gas at z=7, constraining early universe chemical enrichment and ionization states.
Findings
Heavy elements are less than 1/10,000 solar if bound
Gas is mostly neutral hydrogen with negligible metals
Implications for early star formation and cosmic reionization
Abstract
In typical astrophysical environments, the abundance of heavy elements ranges from 0.001 to 2 times the solar concentration. Lower abundances have been seen in select stars in the Milky Way's halo and in two quasar absorption systems at redshift z=3. These are widely interpreted as relics from the early universe, when all gas possessed a primordial chemistry. Before now there have been no direct abundance measurements from the first Gyr after the Big Bang, when the earliest stars began synthesizing elements. Here we report observations of hydrogen and heavy element absorption in a quasar spectrum at z=7.04, when the universe was just 772 Myr old (5.6% its present age). We detect a large column of neutral hydrogen but no corresponding heavy elements, limiting the chemical abundance to less than 1/10,000 the solar level if the gas is in a gravitationally bound protogalaxy, or less than…
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