Magnetic properties and magnetocaloric effects in NaZn13-type La(Fe, Al)13-based compounds

TL;DR

This paper reviews how atomic substitution, magnetic field, and temperature influence the magnetic and magnetocaloric properties of La(Fe, Al)13-based compounds, highlighting their potential for room-temperature magnetic refrigeration.

Contribution

It provides a comprehensive overview of recent progress in tuning magnetic and magnetocaloric effects in LaFe13-xAlx compounds through various substitutions and modifications.

Findings

Al content induces AFM, FM, and mictomagnetic states.

Substitutions can convert AFM to FM coupling.

Maximal entropy change of 13.8 J/kg K at room temperature.

Abstract

In this article, our recent progresses about the effects of atomic substitution, magnetic field and temperature on the magnetic and magnetocaloric properties of the LaFe13-xAlx compounds are reviewed. With the increase of aluminum content, the compounds exhibit successively an antiferromagnetic (AFM), a ferromagnetic (FM), and a mictomagnetic state. Furthermore, the AFM coupling of LaFe13-xAlx can be converted to a FM coupling by substituting Si for Al, Co for Fe and magnetic rare-earth R for La, or introducing interstitial C or H atom. However, low doping levels lead to FM clusters embedded in AFM matrix, and the resultant compounds can undergo, under appropriate applied fields, first an AFM-FM and then a FM-AFM phase transition while heated, with significant magnetic relaxation in the vicinity of the transition temperature. The Curie temperature of LaFe13-xAlx can be shifted to room temperature by choosing appropriate contents of Co, C or H, and strong magnetocaloric effect can be obtained around the transition temperature. For example, for the LaFe11.5Al1.5C0.2H1.0 compound, the maximal entropy change reaches 13.8 J/kg K for a field change of 0-5 T, occurring around the room temperature. It is 42% higher than that of Gd and, therefore, this compound is a promising room-temperature magnetic refrigerant.