A microscopic approach to the nonlinear elasticity of compressed emulsions

TL;DR

This paper investigates the microscopic origins of nonlinear elasticity in compressed emulsions, revealing that microstructural corrections, not anharmonic interactions, drive the nonlinear elastic response.

Contribution

It introduces a microscopic framework linking microstructure changes to nonlinear elasticity in emulsions, emphasizing the role of excess contacts and scaling law corrections.

Findings

Nonlinear elasticity arises from microstructural corrections, not anharmonicity.

Bulk modulus depends on excess contacts created under compression.

Distribution of pressure per particle narrows with increasing global pressure.

Abstract

Using confocal microscopy, we measure the packing geometry and interdroplet forces as a function of the osmotic pressure in a 3D emulsion system. We find that the nonlinear elastic response of the pressure with density is not a result of the anharmonicity in the interaction potential, but of the corrections to the scaling laws of the microstructure away from the critical point. The bulk modulus depends on the excess contacts created under compression, which leads to the correction exponent \alpha=1.5. Microscopically, the nonlinearities manifest themselves as a narrowing of the distribution of the pressure per particle as a function of the global pressure.