Atomistic theoretical study of electronic and polarization properties of elliptical, single and vertically stacked InAs quantum dots

TL;DR

This study uses atomistic simulations to analyze how elliptical shape asymmetry in InAs quantum dots influences their electronic and polarization properties, providing insights for designing optoelectronic devices with tailored polarization responses.

Contribution

It offers a detailed atomistic analysis of how shape asymmetry affects polarization and electronic properties in single and stacked InAs quantum dots, guiding experimental design.

Findings

Elongation of tall QDs allows wider tuning of DOP.

Base elongation orientation controls the sign of DOP.

Elliptical shape can tune either DOP[110] or DOP[-110], not both simultaneously.

Abstract

The demonstration of isotropic polarization response from semiconductor quantum dots (QDs) is a crucial step towards the design of several optoelectronic technologies. Among many parameters that impact the degree of polarization (DOP) of a QD system, the shape asymmetry is a critical factor. We perform multi-million-atom simulations to study the impact of the elliptical shapes on the electronic and polarization properties of single and vertically stacked InAs QDs. The comparison between a low aspect ratio (AR) and a high AR QD reveals that the electronic and the polarization properties strongly depend on the AR of the QD; the elongation of a tall QD allows tuning of the DOP over a much wider range. We then extend our analysis to an experimentally reported vertical stack of nine QDs (9-VSQDs) that has shown significant potential to achieve isotropic polarization properties. We analyse the contribution from the shape asymmetry in the large, experimentally measured, in-plane polarization anisotropy. Our analysis shows that the orientation of the base elongation controls the sign of the DOP; however the magnitude of the base elongation has only a very little impact on the magnitude of the DOP. We further predict that the elliptical shape of the 9-VSQDs can only tune either DOP[110] or DOP[-110] for an isotropic response. Our model results, in agreement with the TEM findings, suggest that the experimentally grown 9-VSQDs has either a circular-base or a slightly [-110] elongated base. Overall the detailed investigation of the DOP as a function of the QD shape asymmetry provides a theoretical guidance for the continuing experimental efforts to achieve tailored polarization properties from the QD nano-structures for the design of optical devices.