Micro-Bullet Assembly: Interactions of Oriented Dipoles in Confined Nematic Liquid Crystal

TL;DR

This study investigates how microbullet-shaped particles interact and assemble in nematic liquid crystals, revealing how surface anchoring, electric fields, and elastic interactions influence their organization.

Contribution

It introduces microbullet particles as a new platform to explore anisotropic colloidal assembly in nematic liquid crystals, demonstrating control over their interactions and structures.

Findings

Parallel dipoles form linear chains in planar cells.

Antiparallel dipoles orient side-to-side and form hexagonal assemblies.

Electric fields can flip microbullets to control their orientation.

Abstract

Microbullet particles, cylinders with one blunt and one spherical end, offer a novel platform to study the effects of anisotropy and curvature on colloidal assembly in complex fluids. Here, we disperse microbullets in 4-cyano-4'-pentylbiphenyl (5CB) nematic liquid crystal (NLC) cells and form oriented elastic dipoles with a nematic point defect located near the curved end. This feature allows us to study particle interactions as a function of dipole alignment. By careful control of the surface anchoring at the particle surface and the confining boundaries, we study the interactions and assembly of microbullets under various conditions. When microbullets with homeotropic surface anchoring are dispersed in a planar cell, parallel dipoles form linear chains parallel to the director, similar to the observations of spherical particles in a planar cell, while antiparallel dipoles orient side-to-side. In a homeotropic cell, however, particles rotate to orient their long axis parallel to the director. When so aligned, parallel dipoles repel and form 2D ordered assemblies with hexagonal symmetry that ripen over time owing to attraction between antiparallel neighbors. Further, we show that the anchoring conditions inside the cell can be altered by application of an electrical field, allowing us to flip microbullets to orient parallel to the director, an effect driven by an elastic torque. Finally, we detail the mechanisms that control the formation of 1D chains and hexagonal lattices with respect to the elasticity of the NLC.