Band gaps and structural properties of graphene halides and their derivates: A hybrid functional study with localized orbital basis sets

TL;DR

This study uses hybrid functional DFT calculations with localized orbital basis sets to analyze the electronic and structural properties of graphene halides, revealing stability trends and potential optoelectronic applications.

Contribution

It demonstrates the effectiveness of localized orbital basis sets in DFT for 2D materials and compares different functionals' predictions of band gaps and stability of graphene halides.

Findings

HSE06 predicts accurate band gaps consistent with experimental data.

Graphene iodide spontaneously decomposes, while fluorographene remains stable.

Certain derivatives like C2FBr and C2HBr are promising for electronic applications.

Abstract

DFT calculations of the electronic structure of graphane and stoichiometrically halogenated graphene derivatives (fluorographene and other analogous graphene halides) show (i) localized orbital basis sets can be successfully and effectively used for such 2D materials; (ii) several functionals predict that the band gap of graphane is greater than that of fluorographene, whereas HSE06 gives the opposite trend; (iii) HSE06 functional predicts quite good values of band gaps w.r.t benchmark theoretical and experimental data; (iv) the zero band gap of graphene is opened by hydrogenation and halogenation and strongly depends on the chemical composition of mixed graphene halides; (v) the stability of graphene halides decreases sharply with increasing size of the halogen atom - fluorographene is stable, whereas graphene iodide spontaneously decomposes. In terms of band gap and stability, the C2FBr, and C2HBr derivatives seem to be promising materials, e.g., for (opto)electronics applications, because their band gaps are similar to those of conventional semiconductors, and they are expected to be stable under ambient conditions. The results indicate that other fluorinated compounds (CaHbFc and CaFbYc, Y = Cl, Br, I) are stable insulators.