Hidden polymorphs drive the vitrification in B2O3

TL;DR

This study uses ab-initio calculations to reveal hidden crystalline polymorphs in B2O3, explaining its unique vitrification behavior and crystallisation anomaly, and suggesting new boron-based nanoporous materials.

Contribution

It uncovers novel B2O3 crystalline polymorphs that explain its vitrification and crystallisation behavior, linking polymorphism to glass formation.

Findings

Discovered new B2O3 crystalline polymorphs with properties similar to glass.

Identified the role of polymorphic degeneracy in vitrification.

Explained the pressure-dependent crystallisation behavior.

Abstract

Understanding the conditions which favor crystallisation or vitrification of liquids has been a long-standing scientific problem. Another connected, and not yet well understood question is the relationship between the glassy and the various possible crystalline forms a system may adopt. In this context, B2O3 is a puzzling case of study since i) it is one of the best glass-forming systems despite an apparent lack of low-pressure polymorphism ii) it vitrifies in a glassy form abnormally different from the only known crystalline phase at ambient pressure iii) it never crystallises from the melt unless pressure is applied, an intriguing behaviour known as the crystallisation anomaly. Here, by means of ab-initio calculations, we discover the existence of novel B2O3 crystalline polymorphs with structural properties similar to the glass and formation energies comparable to the known ambient crystal. The resulting configurational degeneracy drives the system vitrification at ambient pressure. The degeneracy is lifted under pressure, unveiling the origin of the crystallisation anomaly. This work reconciles the behaviour of B2O3 with that from other glassy systems and reaffirms the role played by polymorphism in a system's ability to vitrify. Some of the predicted crystals are cage-like materials entirely made of three-fold rings, opening new perspectives for the synthesis of boron-based nanoporous materials.