Giant magnetocaloric effect in magnetically frustrated EuHo$_2$O$_4$ and EuDy$_2$O$_4$ compounds

TL;DR

This study reports giant magnetocaloric effects in EuHo₂O₄ and EuDy₂O₄ compounds, showing promise as efficient low-temperature magnetic refrigerants due to their large entropy changes and stable properties.

Contribution

First demonstration of large magnetocaloric effects in EuHo₂O₄ and EuDy₂O₄ with potential for low-temperature magnetic refrigeration.

Findings

Maximum entropy change of 30 J kg$^{-1}$ K$^{-1}$ for EuHo₂O₄

Adiabatic temperature change of 16 K for EuDy₂O₄

No thermal or field hysteresis observed

Abstract

We have investigated the magnetic and magnetocaloric properties of EuHo$_2$O$_4$ and EuDy$_2$O$_4$ by magnetization and heat capacity measurements down to 2 K. These compounds undergo a field-induced antiferromagnetic to ferromagnetic transition and exhibit a huge entropy change. For a field change of 0-8 T, the maximum magnetic entropy and adiabatic temperature changes are 30 (25) J kg$^{-1}$ K$^{-1}$ and 12.7 (16) K, respectively and the corresponding value of refrigerant capacity is 540 (415) J kg$^{-1}$ for EuHo$_2$O$_4$ (EuDy$_2$O$_4$). These magnetocaloric parameters also remain large down to lowest temperature measured and are even larger than that for some of the potential magnetic refrigerants reported in the same temperature range for a moderate field change. Moreover, these materials are highly insulating and exhibit no thermal and field hysteresis, fulfilling the necessary conditions for a good magnetic refrigerant in the low-temperature region.