Tentative Detection of Deuterated Methane toward the Low-Mass Protostar IRAS 04368+2557 in L1527
Nami Sakai, Yancy L. Shirley, Takeshi Sakai, Tomoya Hirota, Yoshimasa, Watanabe, and Satoshi Yamamoto

TL;DR
This study reports the tentative first detection of deuterated methane (CH$_3$D) in an interstellar cloud, specifically toward a low-mass protostar, providing insights into molecular abundances and chemical processes in star-forming regions.
Contribution
It presents the first tentative detection of CH$_3$D in an interstellar cloud and estimates its abundance, supporting theories of warm carbon-chain chemistry near protostars.
Findings
Tentative detection of CH$_3$D toward IRAS 04368+2557
Estimated column density and abundance of CH$_3$D
High abundance of CH$_4$ supports warm carbon-chain chemistry
Abstract
The millimeter-wave rotational transition line () of deuterated methane CHD has tentatively been detected toward the low-mass Class 0 protostar IRAS 04368+2557 in L1527 with the Heinrich Hertz Submillimeter Telescope. This is the first detection of CHD in interstellar clouds, if confirmed. The column density and fractional abundance of CHD are determined to be cm and , respectively, where we assume the rotational temperature of 25 K. The column density and fractional abundance of the gaseous CH are estimated to be cm and , respectively, by adopting the molecular D/H ratios of 2--7% reported for various molecules in L1527. The fractional abundance of CH is higher than or comparable to that found in high-mass star-forming cores…
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