Extended defects in natural diamonds: Atomic Force Microscopy investigation

TL;DR

This study uses Atomic Force Microscopy to examine surface features and extended defects in natural diamonds, revealing new defect types and highlighting the role of mechanical twinning alongside dislocation mechanisms in diamond deformation.

Contribution

It provides new insights into the types of defects, including microtwins, in natural diamonds and emphasizes the significance of post-growth deformation processes.

Findings

Identification of new defect types such as anelastic twins

Evidence of microtwins and defect ordering in natural diamonds

Deformation mechanisms include both dislocation slip and mechanical twinning

Abstract

Surfaces of natural diamonds etched in high-pressure experiments in H2O, CO2 and H2O-NaCl fluids were investigated using Atomic Force Microscopy. Partial dissolution of the crystals produced several types of surface features including the well-known trigons and hillocks and revealed several new types of defects. Besides well-known trigons and dissolution hillocks several new types of defects are observed. The most remarkable ones are assigned to anelastic twins of several types. The observation of abundant microtwins, ordering of hillocks and presence of defects presumably related to knots of branched dislocations suggests importance of post-growth deformation events on formation of diamond microstructure. This work confirms previous reports of ordering of extended defects in some deformed diamonds. In addition, the current work shows that natural diamonds deform not only by dislocation mechanism and slip, but also but mechanical twinning. The dominant mechanism should depend on pressure-temperature-stress conditions during diamond transport from the formation domain to the Earth surface.