Ejection of quasi-free electron pairs from the helium atom ground state by single photon absorption

TL;DR

This paper studies single photon double ionization of helium at high energies, revealing a rare quasi-free electron pair emission mechanism predicted decades ago, confirmed by experiments and advanced calculations.

Contribution

It provides the first experimental evidence of the quasi-free PDI mechanism in helium, validating long-standing theoretical predictions.

Findings

Observation of slow doubly charged ions with back-to-back electrons.

Excellent agreement between experimental data and theoretical calculations.

Confirmation of the non-dipole electromagnetic interaction mechanism.

Abstract

We investigate single photon double ionization (PDI) of helium at photon energies of 440 and 800 eV. We observe doubly charged ions with close to zero momentum corresponding to electrons emitted back-to-back with equal energy. These slow ions are the unique fingerprint of an elusive quasi-free PDI mechanism predicted by Amusia et al. nearly four decades years ago [J. Phys. B 8, 1248, (1975)] . It results from the non-dipole part of the electromagnetic interaction. Our experimental data are in excellent agreement with calculations performed using the convergent close coupling and time dependent close coupling methods.