Two-stage Hydrogen Compression Using Zr-based Metal Hydrides

TL;DR

This paper investigates Zr-based AB2-Laves phase alloys for hydrogen compression, focusing on their synthesis, characterization, and pressure-composition behavior to develop an efficient metal hydride-based compressor operating between 20 and 100°C.

Contribution

It introduces a systematic study of Zr-based alloys for hydrogen compression, including synthesis, characterization, and pressure-composition analysis to identify suitable materials for MH-based compressors.

Findings

Alloys successfully synthesized and characterized.

Pressure-Composition-Isotherm data obtained at 20 and 90°C.

Potential alloys identified for hydrogen compression applications.

Abstract

Zr-based AB2-Laves phase type alloys containing the same type of A and B metals, have been prepared from pure elements by melting and subsequent re-melting under argon atmosphere by using a HF-induction levitation furnace. Characterization of the alloys has resulted from powder X-Ray Diffraction (XRD) measurements and SEM/EDX analyses. Systematic PCI (Pressure-Composition-Isotherms) measurements have been recorded at 20 and 90 oC, using a high-pressure Sievert's type apparatus. The purpose of this study is to find a series of alloys promptly forming metal hydrides (MH) with suitable properties in order to build a MH-based hydrogen compressor, working in the same way between 20 and ~100 oC.