{110} Plane Orientation Driven Superior Li-ion Battery Performance and Room Temperature Ferromagnetism in Co3O4 Nanostructures

TL;DR

This study demonstrates that {110} plane-oriented Co3O4 nanostructures exhibit exceptional Li-ion battery performance and room temperature ferromagnetism, linked to surface Co3+ species and defects.

Contribution

It reveals the correlation between nanostructure surface orientation, Co3+ species, and multifunctional properties in Co3O4, highlighting a novel approach to enhance battery and magnetic performance.

Findings

Superior Li-ion battery performance in {110} oriented Co3O4.

Room temperature ferromagnetism associated with surface Co3+ species.

Surface defects and oxygen vacancies influence electronic and magnetic properties.

Abstract

This paper presents synthesis methods and multifunctional properties of porous Co3O4 nanoplatelets and nanowires. Surprisingly, significantly superior Li-ion battery performance compared to other cathode materials is exhibited in the same samples as room temperature ferromagnetism (RTFM). Microstructure observations, and properties measurements and analysis indicate that the as-prepared Co3O4 nanostructures exhibit a spontaneous transformation of their morphology, showing a predominantly {110} plane orientation and preferentially presenting the Co3+ species at the surface at appreciate preparation condition. More Co3+ in an octahedral (O) position exposed on the surface is associated with more Co3+ being Co3+|\cdot (Co3+ with trapped charge carriers) or reduced to Co2+ in the O position due to surface defects or oxygen vacancies, which is possibly the mechanism of excellent electric transport properties then high Li-battery performance; at the same time, reduced to Co2+ or free charge carriers trapped by Co3+|\cdot in the O position are the role of charge carries- mediate ferromagnetism, may be the origin of RTFM as well. These results further show the importance of modifying the nanostructure of surfaces in the preparation of transition metal oxides as multidisciplinary functional materials.