Correlation energy of the one-dimensional Coulomb gas

TL;DR

This paper analyzes the correlation energy of a one-dimensional Coulomb gas confined to a ring, deriving explicit expressions in high- and low-density limits, and proposing an interpolating functional validated by Monte Carlo simulations.

Contribution

It introduces explicit correlation energy expressions for 1D Coulomb gases and develops a new functional bridging high- and low-density regimes.

Findings

Explicit correlation energy expressions in high-density limit.

Asymptotic behavior of correlation energy in thermodynamic limit.

Validated correlation functional against Monte Carlo results.

Abstract

We introduce a new paradigm for finite and infinite strict-one-dimensional uniform electron gases. In this model, $n$ electrons are confined to a ring and interact via a bare Coulomb operator. In the high-density limit (small-$r_s$, where $r_s$ is the Seitz radius), we find that the reduced correlation energy is $\Ec(r_s,n) = \eps^{(2)}(n) + O(r_s)$, and we report explicit expressions for $\eps^{(2)}(n)$. In the thermodynamic (large-$n$) limit of this, we show that $\Ec(r_s) = - \pi^2/360 + O(r_s)$. In the low-density (large-$r_s$) limit, the system forms a Wigner crystal and we find that $\Ec(r_s) = -[\ln(\sqrt{2\pi})-3/4] r_s^{-1} + 0.359933 r_s^{-3/2} + O(r_s^{-2})$. Using these results, we propose a correlation functional that interpolates between the high- and low-density limits. The accuracy of the functional for intermediate densities is established by comparison with diffusion Monte Carlo results. Application to a non-uniform system is also reported.