M\"ossbauer Studies of Coordination Compounds using Synchrotron Radiation

TL;DR

This paper reviews recent synchrotron radiation-based spectroscopic methods, NFS and NIS, for studying M"ossbauer-active complexes, highlighting their advantages and applications in bioinorganic and vibrational spectroscopy.

Contribution

It introduces and discusses the application of NFS and NIS techniques, extending traditional M"ossbauer spectroscopy to new domains and demonstrating their usefulness in various complex systems.

Findings

NFS overcomes limitations of conventional M"ossbauer spectroscopy.

NIS provides site-selective vibrational information.

Applications include spin crossover and bioinorganic complexes.

Abstract

Nuclear resonant forward scattering (NFS) and nuclear inelastic scattering (NIS) of synchrotron radiation are fairly recent spectroscopic methods for the investigation of complexes containing M\"ossbauer-active transition metal ions. NFS, which can be regarded as M\"ossbauer spectroscopy in the time domain, overcomes some limitations of conventional M\"ossbauer spectroscopy as has been demonstrated especially for bioinorganic compounds. NIS extends the energy range of conventional M\"ossbauer spectroscopy to the range of molecular vibrations. Since NIS is sensitive only to the mean-square displacement of M\"ossbauer nuclei it can be used as site-selective vibrational spectroscopy. It complements usefully comparable techniques such as IR or Raman spectroscopy. Examples are given for applications to spin crossover complexes, nitroprusside compounds, heme model complexes and myoglobin.