Theory of ultrafast autoionization dynamics of Fano resonances

TL;DR

This paper develops a theoretical framework for understanding the ultrafast autoionization dynamics of Fano resonances in atoms, using time-resolved wave packet analysis and a pump-probe scheme to measure resonance lifetimes.

Contribution

It introduces a new theoretical approach to characterize the time evolution of autoionization processes and proposes a pump-probe method to extract resonance lifetimes from experimental data.

Findings

Wave packet evolution can be analyzed in energy and coordinate space.

Fano profiles develop during autoionization in the time domain.

Resonance lifetimes can be measured using the proposed pump-probe scheme.

Abstract

We study atomic autoionization processes in the time domain. With the emerging attosecond extreme vacuum ultraviolet and soft x-ray pulses, we first address how to characterize the time evolution of the decay of a discrete state into a degenerate continuum. A short pump beam generates a number of resonance states in a series and the nearby background continuum, and the resultant wave packet evolves with time until the full decay of the bound states. Taking the 2pns(^1P^o) resonance series embedded in the 2sEp(^1P^o) continuum in beryllium atom as an example, the time evolution of the autoionizing wave packet in energy domain and in coordinate space is calculated and analyzed, where Fano profiles build up in the photoelectron energy during the process. A proposed pump-probe scheme assumes that the probe beam ionizes the 2s inner electron in the wave packet. The lifetimes of the resonances and the photoelectron energy distribution can be obtained from the ionization yield versus the time delay of the probe.