Giant Phonon Softening and Enhancement of Superconductivity by Phosphorus Doping of BaNi2As2

TL;DR

Phosphorus doping in BaNi2As2 induces a structural phase change and significantly enhances superconductivity, likely due to phonon softening related to in-plane Ni and As(P) modes.

Contribution

This study demonstrates how phosphorus doping causes a phase transition and boosts superconductivity in BaNi2As2 through phonon softening mechanisms.

Findings

Superconducting transition temperature increases from 0.6 K to 3.3 K with phosphorus doping.

Structural transition from triclinic to tetragonal phase occurs at x=0.067.

Phonon softening is linked to enhanced superconductivity in the doped material.

Abstract

The effects of phosphorus doping on the structural and superconducting phase transitions of BaNi$_2$(As$_{1-x}$P$_x$)$_2$ were studied. The specific heat, resistivity, and magnetic susceptibility were measured. The results revealed an abrupt increase in the superconducting transition temperature ($T_c$) from 0.6 K in the triclinic phase (space group P$\bar{1}$) with less phosphorus (0 $\leq$ $x$ $\leq$ 0.067) to 3.3 K in the tetragonal phase (space group I4/mmm) with more phosphorus ($x$ $\geq$ 0.067). Our data analysis suggests that a doping-induced softening related to an in-plane Ni and As(P) phonon mode is responsible for the enhanced superconductivity in the tetragonal phase.