The Heads and Tails of Buoyant Autocatalytic Balls

TL;DR

This paper investigates how buoyant autocatalytic reaction fronts in fluids create complex flow structures, with numerical simulations revealing the evolution of autocatalytic balls into plume-like formations or their decay based on initial size.

Contribution

It introduces a detailed numerical analysis of autocatalytic balls, highlighting how their size influences the development of plume-like structures or decay, expanding understanding of chemical-hydrodynamic feedback.

Findings

Large autocatalytic balls develop plume-like heads and tails.

Small autocatalytic balls fail to sustain reactions and decay.

Flow evolution depends critically on initial ball size.

Abstract

Buoyancy produced by autocatalytic reaction fronts can produce fluid flows that advect the front position, giving rise to interesting feedback between chemical and hydrodynamic effects. In a large diameter, extended cylinder that is relatively free of boundary constraints, localized initiation of an iodate-arsenous acid (IAA) reaction front on the bottom boundary generates a rising autocatalytic plume. Such plumes have several differences from their non-reactive counterparts. Using numerical simulation, we have found that if reaction is initiated using a spherical ball of product solution well above the bottom boundary, the subsequent flow can evolve much like an autocatalytic plume: the ball develops a reacting head and tail that is akin to the head and conduit of an autocatalytic plume, except that the tail is disconnected from the boundary. In the limit of large initial autocatalytic balls, however, growth of a reacting tail is suppressed and the resemblance to plumes disappears. Conversely, very small balls of product solution fail to initiate sustained fronts and eventually disappear.