Spatial distribution of ions in a linear octopole radio-frequency ion trap in the space-charge limit

TL;DR

This study investigates how ion clouds distribute within a linear octopole RF trap, revealing that ion density and space-charge effects significantly influence the formation of ring or central localization patterns.

Contribution

It provides a quantitative model explaining ion distribution changes due to space-charge effects in a linear octopole RF trap, highlighting the impact on adiabaticity parameters.

Findings

High ion density causes ring-shaped ion distributions.

Ion localization depends on the number of loaded ions.

Space charge reduces the maximum adiabaticity parameter.

Abstract

We have explored the spatial distribution of an ion cloud trapped in a linear octopole radio-frequency (rf) ion trap. The two-dimensional distribution of the column density of stored silver dimer cations was measured via photofragment-ion yields as a function of the position of the incident laser beam over the transverse cross section of the trap. The profile of the ion distribution was found to be dependent on the number of loaded ions. Under high ion-loading conditions with a significant space-charge effect, ions form a ring profile with a maximum at the outer region of the trap, whereas they are localized near the center axis region at low loading of the ions. These results are explained quantitatively by a model calculation based on equilibrium between the space-charge-induced potential and the effective potential of the multipole rf field. The maximum adiabaticity parameter \eta_max is estimated to be about 0.13 for the high ion-density condition in the present octopole ion trap, which is lower than typical values reported for low ion densities; this is probably due to additional instability caused by the space charge.