Probing charge scattering mechanisms in suspended graphene by varying its dielectric environment

TL;DR

This study investigates how the dielectric environment affects charge scattering in suspended graphene, revealing that non-polar liquids enhance mobility by screening impurities, while polar liquids suppress it due to charged ions, and liquids also reduce phonon scattering.

Contribution

It provides experimental evidence on how dielectric environment influences charge scattering mechanisms in suspended graphene, highlighting the role of liquid polarity and dielectric constant.

Findings

High-5 ext{ } ext{dielectric} ext{ } ext{constant} ext{ } ext{liquids} ext{ } ext{increase} ext{ } ext{mobility}

Polar liquids with high 5 ext{ } ext{cause} ext{ } ext{mobility} ext{ } ext{drop}

Liquids suppress out-of-plane flexural phonons, reducing scattering

Abstract

Graphene with high carrier mobility \mu\ is required both for graphene-based electronic devices and for the investigation of the fundamental properties of graphene's Dirac fermions. It is largely accepted that the mobility-limiting factor in graphene is the Coulomb scattering off of charged impurities that reside either on graphene or in the underlying substrate. This is true both for traditional graphene devices on SiO2 substrates and possibly for the recently reported high-mobility suspended and supported devices. An attractive approach to reduce such scattering is to place graphene in an environment with high static dielectric constant \kappa\ that would effectively screen the electric field due to the impurities. However, experiments so far report only a modest effect of high-\kappa\ environment on mobility. Here, we investigate the effect of the dielectric environment of graphene by studying electrical transport in multi-terminal graphene devices that are suspended in liquids with \kappa\ ranging from 1.9 to 33. For non-polar liquids (\kappa <5) we observe a rapid increase of \mu\ with \kappa\ and report a record room-temperature mobility as large as ~60,000 cm2/Vs for graphene devices in anisole (\kappa=4.3), while in polar liquids (\kappa >18) we observe a drastic drop in mobility. We demonstrate that non-polar liquids enhance mobility by screening charged impurities adsorbed on graphene, while charged ions in polar liquids cause the observed mobility suppression. Furthermore, using molecular dynamics simulation we establish that scattering by out-of-plane flexural phonons, a dominant scattering mechanism in suspended graphene in vacuum at room temperature, is suppressed by the presence of liquids. We expect that our findings may provide avenues to control and reduce carrier scattering in future graphene-based electronic devices.