Magnetostructural study of the (Mn,Fe)3(P,Si) system
J. V. Leit\~ao, You Xinmin, L. Caron, E. Br\"uck
TL;DR
This study maps the magnetic and structural phases of the (Mn,Fe)3(Si,P) system, revealing a new hexagonal phase and providing detailed magnetic property data through X-ray diffraction, DSC, and magnetization measurements.
Contribution
It presents the first magnoestructural map of the (Mn,Fe)3(Si,P) system, including the discovery of a novel hexagonal phase and detailed magnetic characterization.
Findings
Identification of a new hexagonal phase in Mn3-xFexSi1-yPy.
Confirmation of known cubic, tetragonal, and orthorhombic phases.
Detailed magnetic properties of the system.
Abstract
Using X-ray diffraction, DSC and magnetization measurements, a magnoestructural map of the (Mn,Fe)3(Si,P) system was assembled and reported in the current paper. Besides the already known cubic phase for Mn3-xFexSi system and the tetragonal and orthorhombic phases for the Mn3-xFexP system, a novel hexagonal phase has been observed for Mn3 xFexSi1-yPy, within the approximate range of 0.2<x<2.0 and 0.2<y<0.9. Magnetization measurements both confirm and further detail the already known properties of the Mn3-xFexSi and Mn3-xFexP systems.
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