Exchange-induced phase separation in Ni-Cu films

TL;DR

This study investigates the magneto-structural properties of Ni-Cu alloy films, revealing partial phase separation driven by magnetic interactions, supported by experimental and theoretical analysis.

Contribution

It provides new experimental evidence of phase separation in Ni-Cu films and a theoretical phase diagram explaining its magnetic origin.

Findings

Partial phase separation observed in Ni-Cu films.

Theoretical phase diagram confirms magnetic origin of separation.

Identification of a metastable region near the ferromagnetic transition.

Abstract

Magneto-structural properties of films of diluted ferromagnetic alloys Ni$_x$Cu$_{1-x}$ in the concentration range $0.7 < x < 1.0$ are studied experimentally. Films deposited by magnetron sputtering show partial phase separation, as evidenced by structural analysis and ferromagnetic resonance measurements. The phase diagram of the Ni$_x$Cu$_{1-x}$ bulk system is obtained using numerical theoretical analysis of the electronic structure, taking into account the inter-atomic exchange interactions. The results confirm the experimentally found partial phase separation, explain it as magnetic in origin, and indicate an additional metastable region connected with the ferromagnetic transition in the system.