Controlling the Frequency-Temperature Sensitivity of a Cryogenic Sapphire Maser Frequency Standard by Manipulating Fe3+ Spins in the Sapphire Lattice
Karim Benmessai, Daniel L. Creedon, Mohamad Mrad, Jean-Michel Le, Floch, Pierre-Yves Bourgeois, Yann Kersal\'e, Vincent Giordano, Michael E., Tobar

TL;DR
This paper demonstrates a method to control the temperature dependence of a cryogenic sapphire maser by manipulating Fe3+ ions, enabling improved frequency stability in these highly precise timekeeping devices.
Contribution
It introduces a novel technique to tune the frequency-temperature dependence of a sapphire maser via Fe3+ ion manipulation, achieving adjustable annulment points.
Findings
Control of the frequency-temperature dependence between 5 to 10 K
Dependence on Fe3+ ion concentration and pump frequency
Enhanced stability potential for cryogenic sapphire masers
Abstract
To create a stable signal from a cryogenic sapphire maser frequency standard, the frequency-temperature dependence of the supporting Whispering Gallery mode must be annulled. We report the ability to control this dependence by manipulating the paramagnetic susceptibility of Fe3+ ions in the sapphire lattice. We show that the maser signal depends on other Whispering Gallery modes tuned to the pump signal near 31 GHz, and the annulment point can be controlled to exist between 5 to 10 K depending on the Fe3+ ion concentration and the frequency of the pump. This level of control has not been achieved previously, and will allow improvements in the stability of such devices.
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