Towards the production of ultracold ground-state RbCs molecules: Feshbach resonances, weakly bound states, and coupled-channel model

TL;DR

This study investigates interspecies scattering and Feshbach resonances in ultracold Rb-87 and Cs-133 mixtures, creating molecules and developing a coupled-channel model to predict and control their interactions for future quantum applications.

Contribution

It provides a comprehensive experimental and theoretical analysis of Feshbach resonances in Rb-Cs mixtures, including molecule creation and a refined coupled-channel interaction model.

Findings

Catalogued 30 Feshbach resonances between 0-667 G.

Created RbCs Feshbach molecules using identified resonances.

Developed a coupled-channel model accurately fitting experimental data.

Abstract

We have studied interspecies scattering in an ultracold mixture of $^{87}$Rb and $^{133}$Cs atoms, both in their lowest-energy spin states. The three-body loss signatures of 30 incoming s- and p-wave magnetic Feshbach resonances over the range 0 to 667 G have been catalogued. Magnetic field modulation spectroscopy was used to observe molecular states bound by up to 2.5 MHz$\times h$. Magnetic moment spectroscopy along the magneto-association pathway from 197 to 182 G gives results consistent with the observed and calculated dependence of the binding energy on magnetic field strength. We have created RbCs Feshbach molecules using two of the resonances. We have set up a coupled-channel model of the interaction and have used direct least-squares fitting to refine its parameters to fit the experimental results from the Feshbach molecules, in addition to the Feshbach resonance positions and the spectroscopic results for deeply bound levels. The final model gives a good description of all the experimental results and predicts a large resonance near 790 G, which may be useful for tuning the interspecies scattering properties. Quantum numbers and vibrational wavefunctions from the model can also be used to choose optimal initial states of Feshbach molecules for their transfer to the rovibronic ground state using stimulated Raman adiabatic passage (STIRAP).