High resolution nuclear magnetic resonance spectroscopy of highly-strained quantum dot nanostructures

TL;DR

This paper introduces high-resolution, non-invasive NMR spectroscopy techniques enabling detailed analysis of strain and composition in individual quantum dots, advancing nanostructure characterization for quantum technologies.

Contribution

Development of sensitive, high-resolution ODNMR methods capable of analyzing as few as 100,000 nuclear spins in strained nanostructures, revealing strain distribution and enhancing spin coherence.

Findings

Measured strain distribution and chemical composition in quantum dots.

Found strain-induced broadening suppresses nuclear spin fluctuations.

Extended nuclear spin coherence times in strained nanostructures.

Abstract

Much new solid state technology for single-photon sources, detectors, photovoltaics and quantum computation relies on the fabrication of strained semiconductor nanostructures. Successful development of these devices depends strongly on techniques allowing structural analysis on the nanometer scale. However, commonly used microscopy methods are destructive, leading to the loss of the important link between the obtained structural information and the electronic and optical properties of the device. Alternative non-invasive techniques such as optically detected nuclear magnetic resonance (ODNMR) so far proved difficult in semiconductor nano-structures due to significant strain-induced quadrupole broadening of the NMR spectra. Here, we develop new high sensitivity techniques that move ODNMR to a new regime, allowing high resolution spectroscopy of as few as 100000 quadrupole nuclear spins. By applying these techniques to individual strained self-assembled quantum dots, we measure strain distribution and chemical composition in the volume occupied by the confined electron. Furthermore, strain-induced spectral broadening is found to lead to suppression of nuclear spin magnetization fluctuations thus extending spin coherence times. The new ODNMR methods have potential to be applied for non-invasive investigations of a wide range of materials beyond single nano-structures, as well as address the task of understanding and control of nuclear spins on the nanoscale, one of the central problems in quantum information processing.