Solution casting method for PVC nano-composites with functionalized single-walled carbon nanotubes1

TL;DR

This paper presents a solution casting method for PVC nanocomposites using functionalized single-walled carbon nanotubes, focusing on dispersion techniques to improve composite quality.

Contribution

It introduces chemical surface modification and surfactant-assisted dispersion methods for SWNTs in PVC to enhance nanocomposite uniformity.

Findings

Improved dispersion stability of SWNTs in PVC solutions.

Enhanced film quality through surface modification.

Effective use of sedimentation stability as a dispersion criterion.

Abstract

Annotation A carbon nanotubes (CNT) filled polymer nanocomposites with their unique physical, mechanical and electro-optical properties has repeatedly discussed in the literature. The main part of this problem is to obtain high quality dispersion of CNTs. If for water-soluble polymers this problem can be considered as solved, it is not so for hydrophobic polymers, and PVC is an important example of this kind. This paper describes the methods of dispersion of SWNTs bundles in PVC, both by the use of specially synthesized surfactants, and by means of chemical surface modification of CNTs. The main criterion for an obtaining of a high degree of dispersion in our experiments is considered the sedimentation stability of non-aqueous organic colloidal solutions, which is essentially necessary for the polymer composites films preparation by solution casting method.