Nanoshells as a high-pressure gauge analyzed to 200 GPa

TL;DR

This paper investigates the potential of nanoshells as high-pressure gauges in diamond anvil cells, demonstrating their advantages and addressing challenges related to pressure media effects through coating strategies.

Contribution

It introduces a coated nanoshell design that remains effective as a pressure gauge up to 200 GPa, overcoming media influence issues present in uncoated nanoshells.

Findings

Nanoshells show measurable pressure-dependent optical responses in vacuum.

Coating nanoshells with dielectric layers shields them from pressure media effects.

Coated nanoshells can reliably measure pressures up to 200 GPa.

Abstract

In this article we present calculations which indicate that nanoshells can be used as a high pressure gauge in Diamond Anvil Cells (DACs). Nanoparticles have important advantages in comparison with the currently used ruby fluorescence gauge. Because of their small dimensions they can be spread uniformly over a diamond surface without bridging between the two diamond anvils. Furthermore their properties are measured by broad band optical transmission spectroscopy leading to a very large signal-to-noise ratio even in the multi-megabar pressure regime where ruby measurements become challenging. Finally their resonant frequencies can be tuned to lie in a convenient part of the visible spectrum accessible to CCD detectors. Theoretical calculations for a nanoshell with a SiO2 core and a golden shell, using both the hybridization model and Mie theory, are presented here. The calculations for the nanoshell in vacuum predict that nanoshells can indeed have a measurable pressure-dependent optical response desirable for gauges.However when the nanoshells are placed in commonly used DAC pressure media, resonance peak positions as a function of pressure are no longer single-valued and depend on the pressure media, rendering them impractical as a pressure gauge. To overcome these problems an alternative nanoparticle is studied: coating the nanoshell with an extra dielectric layer (SiO2) provides an easy way to shield the pressure gauge from the influence of the medium, leaving the compression of the particle due to the pressure as the main effect on the spectrum. We have analyzed the response to pressure up to 200 GPa. We conclude that a coated nanoshell could provide a new gauge for high-pressure measurements that has advantages over current methods.