Magnetic behavior of bulk and fine particles of RCr2Si2C (R = La, Ce)compounds: possible magnetic ordering from Cr

TL;DR

This study investigates the magnetic properties of RCr2Si2C (R=La, Ce) compounds in bulk and nano forms, revealing itinerant magnetic ordering of Cr and size-dependent valence and heavy-fermion behaviors.

Contribution

It provides new insights into how nano-sizing affects magnetic ordering and valence states in RCr2Si2C compounds, highlighting the suppression of Cr magnetic order and changes in Ce valence.

Findings

Cr exhibits itinerant magnetic order below 20 K in bulk form.

Nano-sizing suppresses Cr magnetic ordering.

Ce shows valence change and enhanced heavy-fermion behavior in nano form.

Abstract

The magnetic behavior of the quaternary compounds, RCr2Si2C (R = La, Ce), has been investigated by magnetization (M) and heat-capacity (C) measurements (1.8-300 K) in the bulk polycrystals and nano forms (<1 {\mu}m) obtained by high-energy balling. Our finding is that Cr appears to exhibit magnetic ordering of an itinerant type at low temperatures (<20 K) in the bulk form, as inferred from a combined look at all the data. The magnetic ordering gets gradually suppressed with increasing milling time. Evidence for a mixed-valence state of Ce for the bulk form is obtained from the tendency of magnetic susceptibility to exhibit a maximum above 300 K. However, this feature vanishes in the nano form, which exhibits a Curie-Weiss behavior above 200 K as though Ce tends towards trivalency in these fine particles; in addition, there is a weak upturn in C/T below 10 K in the bulk, which becomes very prominent in the milled Ce-based specimens at lower temperatures, as though heavy-fermion behavior gets stronger in smaller particles.