Quadrupolar spectra of nuclear spins in strained InGaAs quantum dots

TL;DR

This paper provides an atomistic analysis of strain-induced quadrupolar effects on nuclear spins in InGaAs quantum dots, revealing how structural features influence NMR spectra and nuclear spin polarization.

Contribution

It offers new insights into how QD geometry, composition, and interfaces affect quadrupolar interactions and NMR spectra, aiding future quantum dot nuclear magnetic resonance studies.

Findings

High aspect ratio enhances quadrupolar interaction.

Alloy mixing increases biaxiality and tilt, reduces quadrupolar energy.

In nuclei dominate NMR signals, with specific field thresholds for depolarization.

Abstract

Self-assembled quantum dots (QDs) are born out of lattice mismatched ingredients where strain plays an indispensable role. Through the electric quadrupolar coupling, strain affects the magnetic environment as seen by the nuclear spins. To guide prospective single-QD nuclear magnetic resonance (NMR) as well as dynamic nuclear spin polarization experiments, an atomistic insight to the strain and quadrupolar field distributions is presented. A number of implications of the structural and compositional profile of the QD have been identified. A high aspect ratio of the QD geometry enhances the quadrupolar interaction. The inclined interfaces introduce biaxiality and the tilting of the major quadrupolar principal axis away from the growth axis; the alloy mixing of gallium into the QD enhances both of these features while reducing the quadrupolar energy. Regarding the NMR spectra, both Faraday and Voigt geometries are investigated, unraveling in the first place the extend of inhomogeneous broadening and the appearance of the normally-forbidden transitions. Moreover, it is shown that from the main extend of the NMR spectra the alloy mole fraction of a single QD can be inferred. By means of the element-resolved NMR intensities it is found that In nuclei has a factor of five dominance over those of As. In the presence of an external magnetic field, the borderlines between the quadrupolar and Zeeman regimes are extracted as 1.5 T for In and 1.1 T for As nuclei. At these values the nuclear spin depolarization rates of the respective nuclei get maximized due to the noncollinear secular hyperfine interaction with a resident electron in the QD.