The role of OH in the chemical evolution of protoplanetary disks. I. The comet-forming region

TL;DR

This study investigates how enhanced cosmic ray-induced UV photons increase OH formation, affecting the chemical composition of protoplanetary disk midplanes at 10 AU, with implications for comet formation.

Contribution

It provides a more accurate estimate of cosmic ray-induced UV flux and explores its impact on gas-grain chemistry and molecule formation in protoplanetary disks.

Findings

Enhanced OH abundance influences ice composition at 10 AU.

Model results align with observed cometary molecule abundances.

Physical conditions for comet formation are constrained by chemical modeling.

Abstract

Context. Time dependent gas-grain chemistry can help us understand the layered structure of species deposited onto the surface of grains during the lifetime of a protoplanetary disk. The history of trapping important quantities of carbon- and oxygen-bearing molecules onto the grains is of special significance for the formation of more complex (organic) molecules on the surface of grains. Aims. Among other processes, cosmic ray-induced UV photo-processes can lead to the efficient formation of OH. Using a more accurate treatment of cosmic ray-gas interactions for disks, we obtain an increased cosmic ray-induced UV photon flux of 3.8x10^5 photons cm^-2s^-1 for a cosmic-ray ionization rate of H2 value of 5x10^-17 s^-1 (compared to previous estimates of 10^4 photons cm^-2s^-1 based on ISM dust properties). We explore the role of the enhanced OH abundance on the gas-grain chemistry in the midplane of the disk at 10 AU, which is a plausible location for comet formation. We focus on studying the formation/destruction pathways and timescales of the dominant chemical species. Methods. We solve the chemical rate equations based on a gas-grain chemical network and correcting for the enhanced cosmic rayinduced UV field. This field is estimated from an appropriate treatment of dust properties in a protoplanetary disk, as opposed to previous estimates that assume an ISM-like grain size distribution. We also explore the chemical effects of photo-desorption of water ice into OH+H. Results. Near the end of the disk's lifetime our chemical model yields H2O, CO, CO2 and CH4 ice abundances at 10 AU (consistent with a midplane density of 10^10 cm^-3 and a temperature of 20 K) that are compatible with measurements of the chemical composition of cometary bodies for a [C/O] ratio of 0.16. Such comparison provides constraints on the physical conditions in which comets were formed.