New phase diagrams for dense carbon-oxygen mixtures and white dwarf evolution

TL;DR

This study investigates how a new phase diagram for dense carbon-oxygen mixtures affects white dwarf cooling ages, revealing significant differences that impact stellar age estimates and globular cluster dating.

Contribution

The paper applies a recently derived molecular dynamics phase diagram to white dwarf evolution models, showing its effects on cooling delays compared to previous diagrams.

Findings

Energy release from phase separation is smaller with the new phase diagram.

Cooling delays are approximately half of those predicted by older models.

Implications for white dwarf cosmochronology and globular cluster age estimates.

Abstract

Cool white dwarfs are reliable and independent stellar chronometers. The most common white dwarfs have carbon-oxygen dense cores. Consequently, the cooling ages of very cool white dwarfs sensitively depend on the adopted phase diagram of the carbon-oxygen binary mixture. A new phase diagram of dense carbon-oxygen mixtures appropriate for white dwarf interiors has been recently obtained using direct molecular dynamics simulations. In this paper, we explore the consequences of this phase diagram in the evolution of cool white dwarfs. To do this we employ a detailed stellar evolutionary code and accurate initial white dwarf configurations, derived from the full evolution of progenitor stars. We use two different phase diagrams, that of Horowitz et al. (2010), which presents an azeotrope, and the phase diagram of Segretain & Chabrier (1993), which is of the spindle form. We computed the evolution of 0.593 and 0.878M_sun white dwarf models during the crystallization phase, and we found that the energy released by carbon-oxygen phase separation is smaller when the new phase diagram of Horowitz et al. (2010) is used. This translates into time delays that are on average a factor about 2 smaller than those obtained when the phase diagram of Segretain & Chabrier (1993) is employed. Our results have important implications for white dwarf cosmochronology, because the cooling ages of very old white dwarfs are different for the two phase diagrams. This may have a noticeable impact on the age determinations of very old globular clusters, for which the white dwarf color-magnitude diagram provides an independent way of estimating their age.