Time-keeping with electron spin states in diamond
Jonathan S. Hodges, Dirk Englund

TL;DR
This paper introduces a solid-state frequency standard using nitrogen-vacancy centers in diamond, offering comparable stability to atomic clocks and potential for chip-scale integration.
Contribution
The work demonstrates a new solid-state spin-based frequency standard with stability comparable to atomic standards, suitable for miniaturization.
Findings
Achieved an Allan deviation of 1E-12 with current methods.
Projected stability exceeding 1E-14 with improvements.
Compatible with chip-scale device integration.
Abstract
Frequency standards based on atomic states, such as Rb or Cs vapors, or single trapped ions, are the most precise measures of time. Here we introduce a complementary device based on spins in a solid-state system - the nitrogen-vacancy defect in single crystal diamond. We show that this system has comparable stability to portable atomic standards and is readily incorporable as a chip-scale device. Using a pulsed spin-echo technique, we anticipate an Allan deviation of {\sigma}_y =1E-12 ({\tau})^(-1/2) with current photoluminescence detection methods and posit exceeding 1E-14 with improved diamond material processing and nanophotonic engineering.
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