Structural and Optical properties of Zn(1-x)MgxO nanocrystals obtained by low temperature method

TL;DR

This study investigates the structural and optical properties of Mg-doped ZnO nanocrystals synthesized at low temperature, revealing phase segregation effects and their impact on optical emissions.

Contribution

It demonstrates successful low-temperature synthesis of Zn1-xMgxO nanocrystals up to x=0.17 without phase segregation and analyzes how Mg doping influences structural and optical properties.

Findings

Bandgap increases with Mg content, reaching 4 eV at x=0.17.

Green emission intensity varies with Mg concentration, quenching at higher levels.

Phase segregation leads to Mg(OH)2 shell formation, affecting green emission.

Abstract

In this paper we report structural and optical properties of Magnesium substituted Zinc Oxide (Zn1-xMgxO) nanocrystals (~10-12nm) synthesized by low temperature route. In the low temperature synthesis route it was possible to reach x = 0.17 without segregation of Mg rich phase. The exact chemical composition has been established by quantitative analysis. Rietveld analysis of the XRD data confirms the Wurzite structure and a continuous compaction of the lattice (in particular the c-axis parameter) as x increases. There is an enhancement of the strain in the lattice as the Mg is substituted. The bandgap also gets enhanced as x is increased and reaches a value of 4eV for x = 0.17. From the TEM and the XRD data it has been concluded that when there is a phase segregation for x > 0.17, there is a shell of Mg(OH)2 on the ZnO. The absorption also shows persistence of the excitoinc absorption on Mg substitution. The nanocrystals show near band edge photo luminescence (PL) at room temperature which shows blue shift on Mg incorporation. In addition to the near band edge emission the ZnO and Zn1-xMg xO alloy nanocrystals show considerable emission in the blue-green region at wavelength of ~550 nm. We find that the relative intensity of the green emission increases with the Mg concentration for very low x (upto x = 0.05) and on further increase of the Mg concentration there is a sharp decrease of relative intensity of the green emission eventually leading to a complete quenching of blue emission. It is concluded that due to phase segregation (for x \geq 0.20), the formation of the shell of Mg(OH)2 on the ZnO leads to quenching of the green emission .However, this shell formation does not have much effect on the near band edge PL.