Dealloying of Platinum-Aluminum Thin Films Part II. Electrode Performance

TL;DR

This study investigates the fabrication of porous Pt/Al electrodes via dealloying for solid oxide fuel cells, highlighting high initial performance and degradation at higher temperatures due to oxidation.

Contribution

It demonstrates a novel dealloying method to produce high-surface-area Pt/Al electrodes with enhanced initial performance in fuel cells.

Findings

High initial oxygen reduction performance at 523 K

Performance degradation at 673 K and 873 K due to Al oxidation

Porous structure enhances three-phase boundary length

Abstract

Highly porous Pt/Al thin film electrodes on yttria stabilized zirconia electrolytes were prepared by dealloying of co-sputtered Pt/Al films. The oxygen reduction capability of the resulting electrodes was analyzed in a solid oxide fuel cell setup at elevated temperatures. During initial heating to 523 K exceptionally high performances compared to conventional Pt thin film electrodes were measured. This results from the high internal surface area and large three phase boundary length obtained by the dealloying process. Exposure to elevated temperatures of 673 K or 873 K gave rise to degradation of the electrode performance, which was primarily attributed to the oxidation of remaining Al in the thin films.