Effective Classical Hamiltonian from Perturbatively Defined Path Integral
Michael Bachmann

TL;DR
This paper introduces a perturbative approach to phase space path integrals that avoids slicing, enabling efficient calculation of short-time quantum amplitudes and effective classical Hamiltonians, demonstrated on the harmonic oscillator.
Contribution
It presents a novel perturbative formalism for phase space path integrals that simplifies calculations of quantum amplitudes and effective Hamiltonians without slicing.
Findings
Derived a short-time expansion for quantum amplitudes
Calculated the effective classical Hamiltonian for the harmonic oscillator
Provided a new method for high-temperature density matrix approximation
Abstract
Introducing a perturbative definition, phase space path integrals can be calculated without slicing. This leads to a short-time expansion of the quantum-mechanical path amplitude, or a high-temperature expansion of the unnormalized density matrix, respectively. We use the proposed formalism to calculate the effective classical Hamiltonian for the harmonic oscillator.
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Taxonomy
TopicsQuantum, superfluid, helium dynamics · Advanced Chemical Physics Studies · Spectroscopy and Quantum Chemical Studies
