High resolution x-ray scattering studies of structural phase transitions in Cr-doped BaFe2As2

TL;DR

This study investigates how chromium doping affects the structural and magnetic phase transitions in BaFe2As2 using high-resolution x-ray scattering, revealing a crossover from itinerant to localized magnetism around x ~ 0.05.

Contribution

It provides detailed insights into the doping-dependent suppression of structural transition and the magnetostructural crossover in Cr-doped BaFe2As2.

Findings

Cr doping suppresses the structural transition temperature (Ts).

Orthorhombic strain decreases with increased Cr concentration.

A magnetostructural crossover occurs at x ~ 0.05, shifting magnetic behavior.

Abstract

We have performed high resolution x-ray scattering measurements on single crystal samples of Ba(Fe(1-x)Cr(x))2As2 (x = 0 to 0.335). These measurements examine the effect of Cr-doping on the high temperature tetragonal (I4/mmm) to low temperature orthorhombic (Fmmm) structural phase transition of the parent compound BaFe2As2. Increasing Cr concentration is found to suppress the structural transition temperature (Ts), and reduce the magnitude of the orthorhombic strain (delta). The doping dependence of the orthorhombic strain, combined with complementary measurements of the high temperature magnetic susceptibility, suggests the presence of a magnetostructural crossover at x ~ 0.05. In particular, this crossover appears to mark a shift from strong to weak orthorhombicity and from predominantly itinerant to localized magnetic behavior.