Langmuir-Blodgett Monolayers of Cationic Dyes in the Presence and Absence of Clay Mineral Layers: N,N'-Dioctadecyl Thiacyanine, Octadecyl Rhodamine B and Laponite

TL;DR

This study investigates the formation and properties of Langmuir-Blodgett monolayers of cationic dyes NK and RhB18, with and without clay mineral layers, revealing aggregation behaviors and energy transfer mechanisms.

Contribution

It provides new insights into dye aggregation and fluorescence energy transfer in LB films influenced by clay mineral layers, highlighting optimal conditions for energy transfer.

Findings

NK forms H- and J-aggregates in monolayers.

Fluorescence resonance energy transfer occurs from NK to RhB18.

Optimal energy transfer at 90 mol% NK + 10 mol% RhB18.

Abstract

Langmuir-Blodgett (LB) films of N,N'-dioctadecyl thiacyanine perchlorate (NK) and octadecyl rhodamine B chloride (RhB18) and their mixtures in the presence and absence of clay mineral layers were investigated by recording surface pressure - area isotherms and by UV-Vis and fluorescence spectroscopies. The isotherms of NK, RhB18 and their mixtures are characteristic for liquid expanded state behaviour with repulsive interactions between the two cationic dyes. In the presence of laponite the isotherms show liquid expanded and condensed state behaviour. In laponite dispersions and in monolayers, NK has a strong tendency to aggregate with formation of H- and J- aggregates. The absorption and fluorescence maxima of the monomers in the films are at 435 nm and at 480 nm; H-dimer have an absorption maximum around 410 nm and do not fluoresce. J-dimers are present in all the films with absorption maximum at 461 nm and fluorescence at 463 nm. RhB18 is mainly present as monomers in the LB films with an absorption maximum at 576 nm and fluorescence at 595 nm. Fluorescence resonance energy transfer from NK to RhB18 has been observed in clay dispersions and in films with and without laponite. The optimum condition for NK RhB18 fluorescence energy transfer in the films is 90 mol% NK + 10 mol% RhB18.