Influence of cross-section geometry and wire orientation on the phonon shifts in ultra-scaled Si nanowires

TL;DR

This study investigates how the shape, size, and orientation of ultra-scaled silicon nanowires influence their phonon shifts, revealing shape-dependent acoustic and optical phonon behaviors using a modified valence force field model.

Contribution

It provides a detailed analysis of phonon shifts in Si nanowires based on cross-section geometry and orientation, highlighting the shape-dependent phonon behavior.

Findings

Triangular SiNWs exhibit minimal acoustic hardening and maximum optical softening.

Acoustic phonon shifts depend strongly on wire orientation.

Optical phonon softening is independent of wire orientation.

Abstract

Engineering of the cross-section shape and size of ultra-scaled Si nanowires (SiNWs) provides an attractive way for tuning their structural properties. The acoustic and optical phonon shifts of the free-standing circular, hexagonal, square and triangular SiNWs are calculated using a Modified Valence Force Field (MVFF) model. The acoustic phonon blue shift (acoustic hardening) and the optical phonon red shift (optical softening) show a strong dependence on the cross-section shape and size of the SiNWs. The triangular SiNWs have the least structural symmetry as revealed by the splitting of the degenerate flexural phonon modes and The show the minimum acoustic hardening and the maximum optical hardening. The acoustic hardening, in all SiNWs, is attributed to the decreasing difference in the vibrational energy distribution between the inner and the surface atoms with decreasing cross-section size. The optical softening is attributed to the reduced phonon group velocity and the localization of the vibrational energy density on the inner atoms. While the acoustic phonon shift shows a strong wire orientation dependence, the optical phonon softening is independent of wire orientation.