The penetrable square-well model: extensive versus non-extensive phase

TL;DR

This study explores the phase behavior of the penetrable square-well fluid, revealing stability conditions, metastable regions, and a collapse into a non-extensive phase at high penetrability through Monte Carlo simulations.

Contribution

It demonstrates the stability threshold of the model and characterizes the non-extensive phase, providing new insights into the system's thermodynamic behavior.

Findings

Model is stable at low penetrability, behaving like the square-well model.

Existence of a metastable region with fluid-fluid and fluid-solid transitions.

High penetrability leads to collapse into a non-extensive phase with particle clusters.

Abstract

The phase diagram of the penetrable square-well fluid is investigated through Monte Carlo simulations of various nature. This model was proposed as the simplest possibility of combining bounded repulsions at short scale and short-range attractions. We prove that the model is thermodynamically stable for sufficiently low values of the penetrability parameter, and in this case the system behaves similarly to the square-well model. For larger penetration, there exists an intermediate region where the system is metastable, with well defined fluid-fluid and fluid-solid transitions, at finite size, but eventually becomes unstable in the thermodynamic limit. We characterize the unstable non-extensive phase appearing at high penetrability, where the system collapses into an isolated blob of a few clusters of many ovelapping particles each.