Mechanism of Thermal Conductivity Reduction in Few-Layer Graphene

TL;DR

This study investigates how adding layers to graphene reduces its thermal conductivity by analyzing phonon scattering processes, revealing that interlayer interactions significantly impact heat transport.

Contribution

It provides a detailed theoretical analysis of phonon scattering mechanisms in few-layer graphene, highlighting the role of interlayer coupling in thermal conductivity reduction.

Findings

Weak interlayer coupling opens new three-phonon scattering channels.

ZA phonons still dominate thermal conductivity despite layering.

Thermal conductivity reduction mainly due to lower contributions of higher-order overtones.

Abstract

Using the linearized Boltzmann transport equation and perturbation theory, we analyze the reduction in the intrinsic thermal conductivity of few-layer graphene sheets accounting for all possible three-phonon scattering events. Even with weak coupling between layers, a significant reduction in the thermal conductivity of the out-of-plane acoustic modes is apparent. The main effect of this weak coupling is to open many new three-phonon scattering channels that are otherwise absent in graphene. However, reflection symmetry is only weakly broken with the addition of multiple layers, and ZA phonons still dominate thermal conductivity. We also find that reduction in thermal conductivity is mainly caused by lower contributions of the higher-order overtones of the fundamental out-of-plane acoustic mode. The results compare remarkably well over the entire temperature range with measurements of graphene and graphite.