Magnetic excitations in L-edge resonant inelastic x-ray scattering from cuprate compounds

TL;DR

This paper investigates magnetic excitations in cuprate compounds using L-edge RIXS, deriving spectra related to spin correlations, and compares theoretical predictions with experimental data to reveal multi-magnon contributions.

Contribution

The study introduces a detailed theoretical framework for interpreting RIXS spectra in cuprates, including multi-magnon effects and higher-order corrections, advancing understanding of magnetic excitations.

Findings

RIXS spectra are expressed as dynamical structure factors of transverse spins.

Three-magnon excitations significantly contribute to high-energy spectral features.

Theoretical spectra agree with experimental observations of asymmetry and width in magnon peaks.

Abstract

We study the magnetic excitation spectra in L-edge resonant inelastic x-ray scattering (RIXS) from undoped cuprates. We analyze the second-order dipole allowed process that the strong perturbation works through the intermediate state in which the spin degree of freedom is lost at the core-hole site. Within the approximation neglecting the perturbation on the neighboring sites, we derive the spin-flip final state in the scattering channel with changing the polarization, which leads to the RIXS spectra expressed as the dynamical structure factor of the transverse spin components. We assume a spherical form of the spin-conserving final state in the channel without changing the polarization, which leads to the RIXS spectra expressed as the 'exchange'-type multi-spin correlation function. Evaluating numerically the transition amplitudes to these final states on a finite-size cluster, we obtain a sizable amount of the transition amplitude to the spin-conserving final state in comparison with that to the spin-flip final state. We treat the itinerant magnetic excitations in the final state by means of the 1/S-expansion method. Evaluating the higher-order correction with 1/S, we find that the peak arising from the one-magnon excitation is reduced with its weight, and the continuous spectra arising from the three-magnon excitations come out. The interaction between two magnons is treated by summing up the ladder diagrams. On the basis of these results, we analyze the L_3-edge RIXS spectra in Sr_2CuO_2Cl_2 in comparison with the experiment. It is shown that the three-magnon excitations as well as the two-magnon excitations give rise to the intensity in the high energy side of the one-magnon peak, making the spectral shape asymmetric with wide width, in good agreement with the experiment.