Structure-related transport properties of A-site ordered perovskite Sr3ErMn4-xGaxO10.5-d
W. Kobayashi, and T. Ishibashi

TL;DR
This study investigates how A-site ordering affects the transport and magnetic properties of Sr3ErMn4-xGaxO10.5-d, revealing that disorder significantly reduces resistivity and influences magnetic behavior.
Contribution
It demonstrates the impact of A-site disorder on resistivity and magnetic properties in Sr3ErMn4-xGaxO10.5-d, highlighting the role of structural order in transport phenomena.
Findings
A-site ordered phase appears above x=1.
Disordered phase shows significantly lower resistivity.
Magnetic properties consistent with Mn3+ antiferromagnetic insulator.
Abstract
We report x-ray diffraction, resistivity, thermopower, and magnetization of Sr3ErMn4-xGaxO10.5-d, in which A-site ordered tetragonal phase appears above x=1, and reveal that the system exhibits typical properties seen in the antiferromagnetic insulator with Mn3+. We succeed in preparing both A-site ordered and disordered phases for x=1 in different preparation conditions, and observe a significant decrease of the resistivity in the disordered phase. We discuss possible origins of the decrease focusing on the dimensionality and the disordered effect.
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