Structural changes at the semiconductor-insulator phase transition in the single layered La0.5Sr1.5MnO4 perovskite

TL;DR

This study reveals that a structural phase transition from tetragonal to orthorhombic symmetry in La0.5Sr1.5MnO4 drives its semiconductor-insulator transition, involving specific soft modes and charge disproportionation without requiring orbital ordering.

Contribution

It provides a detailed symmetry-mode analysis linking structural changes to electronic transition mechanisms in La0.5Sr1.5MnO4, highlighting the roles of soft modes and charge disproportionation.

Findings

Structural transition from tetragonal to orthorhombic phases.

Charge disproportionation of about 0.15 electrons between Mn sites.

Resonant scattering explained by local geometrical anisotropy without orbital ordering.

Abstract

The semiconductor-insulator phase transition of the single-layer manganite La0.5Sr1.5MnO4 has been studied by means of high resolution synchrotron x-ray powder diffraction and resonant x-ray scattering at the Mn K edge. We conclude that a concomitant structural transition from tetragonal I4/mmm to orthorhombic Cmcm phases drives this electronic transition. A detailed symmetry-mode analysis reveals that condensation of three soft modes -Delta_2(B2u), X1+(B2u) and X1+(A)- acting on the oxygen atoms accounts for the structural transformation. The Delta_2 mode leads to a pseudo Jahn-Teller distortion (in the orthorhombic bc-plane only) on one Mn site (Mn1) whereas the two X1+ modes produce an overall contraction of the other Mn site (Mn2) and expansion of the Mn1 one. The X1+ modes are responsible for the tetragonal superlattice (1/2,1/2,0)-type reflections in agreement with a checkerboard ordering of two different Mn sites. A strong enhancement of the scattered intensity has been observed for these superlattice reflections close to the Mn K edge, which could be ascribed to some degree of charge disproportion between the two Mn sites of about 0.15 electrons. We also found that the local geometrical anisotropy of the Mn1 atoms and its ordering originated by the condensed Delta_2 mode alone perfectly explains the resonant scattering of forbidden (1/4,1/4,0)-type reflections without invoking any orbital ordering.